微波消解―ICP―MS法测土壤和水系沉积物样品中的碘          下载免费PDF全文

孙霞  谭微  贾双琳  杨刚  周小林 《贵州地质》2018,35(3):257-261

介绍了用微波消解处理土壤和水系沉积物样品,用电感耦合等离子质谱仪(ICP-MS)快速高效测试碘的方法。方法的检出限为0. 012μg/g。所选的12个土壤和水系沉积物国家一级标准物质12次测定,除GBW07307a的RSD小于10%外,其余RSD值均小于5%,12次测试的平均值和标准值对数差绝对值均小于0. 05。方法加标回收率在98. 6%104. 6%之间。  相似文献   

微波消解-电感耦合等离子体质谱法测定海泡石中的稀土元素   总被引：3，自引：3，他引：0  

张楠  徐铁民  吴良英  魏双  方蓬达  王家松 《岩矿测试》2018,37(6):644-649

海泡石是一种纤维状含水的富镁硅酸盐黏土矿,其中的稀土元素含量在1×10~(-7)～1×10~(-5)之间,目前还没有建立海泡石中稀土元素的国家标准分析方法。测定岩石中的稀土元素主要是采用电感耦合等离子体质谱法(ICP-MS),样品前处理一般采用封闭溶矿和碱熔,但这两种处理方法耗时较长,效率不高。本文通过比较硝酸-氢氟酸-过氧化氢、硝酸-氢氟酸、硝酸-过氧化氢三种样品前处理方法,确定使用硝酸-氢氟酸溶矿,然后进行微波消解同时赶去氢氟酸,避免氢氟酸与稀土元素生成难溶的氟化物,再采用ICP-MS法测定15种稀土元素的含量。由于海泡石中的镁含量较高,为降低基体效应,以~(103)Rh和~(185)Re作内标补偿基体效应和校正灵敏度漂移,各元素测定值的准确性显著提高,回收率为91. 2%～110. 9%,检出限为0. 002～0. 011μg/L,精密度≤2. 79%。本方法与封闭酸溶ICP-MS法的分析结果吻合较好,且用酸量少(7 mL),溶矿效率高(1 h),检出限更低。  相似文献   

Cross-Correlation Detection of Point Sources in the WMAP First Year Data     

Jian-Yin Nie  Shuang-Nan Zhang  Department of Physics  Center for Astrophysics  Tsinghua University  Beijing  Key Laboratory of Particle Astrophysics  Institute of High Energy Physics  Chinese Academy of Sciences  Beijing 《中国天文和天体物理学报》2007,7(2):199-208

We apply a Cross-Correlation (CC) method developed previously for detecting gamma-ray point sources to the WMAP first year data by using the Point-Spread Function of WMAP and obtain a full sky CC coefficient map. We find that the CC method is a pow- erful tool to examine the WMAP foreground residuals which can be further cleaned accord- ingly. Evident foreground signals are found in the WMAP foreground cleaned maps and the Tegmark cleaned map. In this process 101 point sources are detected, and 26 of them are new sources additional to the originally listed WMAP 208 sources. We estimate the ?ux of these new sources and verify them by another method. As a result, a revised mask file based on the WMAP first year data is produced by including these new sources.  相似文献   

弱流场调制下的海面微波散射模拟研究          下载免费PDF全文

吕伟艳  赵朝方  杜涛 《海洋科学》2008,32(7):57-61

根据海面微波散射的多尺度模型以及波流相互作用理论，对一维弱流场调制下的海面微波散射截面进行了数值模拟。结果表明，利用数值方法直接求解波作用量方程获得的海浪调制谱并结合多尺度模型可以较好地模拟弱流场引起的雷达散射截面的变化。内波等海洋现象调制了海浪谱，使得雷达散射截面反映出这些海洋特征，整个调制过程的模拟对于分析这些海洋现象并更好地利用其雷达数据具有重要意义。  相似文献   

Quantum peculiarities of the primordial hydrogen recombination     

V. K. Dubrovich 《Astronomy Letters》2007,33(10):645-648

Some problems of the two-photon decay of highly excited atomic hydrogen and helium levels are considered. The necessary accuracy of calculating the transition probabilities is shown to require abandoning the purely dipole approximation in the theory of atomic hydrogen radiation. The range of applicability of the perturbation theory to this process is discussed. We suggest a new mechanism of the Lyman photon redistribution due to very close locations of the 20P and 19P levels in the hydrogen and deuterium atoms, respectively (hydrogen-deuterium resonance).  相似文献   

光谱对许氏平鲉消化代谢节律及生理应激研究          下载免费PDF全文

房莹莹  陈璐璐  刘松涛  孙飞  吴燕玲  李鑫  刘鹰  马贺 《海洋科学》2023,47(10):94-111

为探究不同光谱下许氏平鲉的消化代谢水平及外周激素节律,在5种光谱(红光、绿光、黄光、蓝光、白光,光周期12L∶12D)下,通过对许氏平鲉的血清、肠道、肝脏进行24 h (8:00,12:00,16:00,20:00,24:00)取样,结果显示:不同的光谱下许氏平鲉的消化代谢酶活性除胰蛋白酶(TRY)外均具有节律性,红光、黄光下α-淀粉酶(α-AMS)、脂肪酶(LPS)活性的峰值相位与白光组相比左移;胰蛋白酶活性无时间差异性;在绿光、黄光及红光下乳酸脱氢酶(LDH)活性的峰值相位与白光组相比发生左移,在五种光谱环境中,红、黄光影响消化酶活性峰值提前出现;丙酮酸激酶(PK)活性在绿、蓝及红光下峰值相位左移;己糖激酶(HK)的活性在绿、蓝、黄光下,其峰值相位与白光组相比发生左移,在五种光谱环境中,绿、蓝光影响代谢酶活性类峰值提前出现。许氏平鲉血清中褪黑素含量呈现昼低夜高分泌水平;皮质醇的含量表现为在白天降低,午夜显著升高至最高值后又持续降低。峰值相位的改变预示着生理节律的变动,以上结果表明不同光谱可以影响鱼类的生理代谢节律,在今后养殖过程中需要充分考虑光谱对养殖生物的生物学作用,进而制定更为合理的光照条件。  相似文献   

Spatial variability of snowmelt timing from AMSR‐E and SSM/I passive microwave sensors,Pelly River,Yukon Territory,Canada     

Joan M. Ramage  Jeremy D. Apgar  Rose A. McKenney  Wade Hanna 《水文研究》2007,21(12):1548-1560

Spring snow melt run‐off in high latitude and snow‐dominated drainage basins is generally the most significant annual hydrological event. Melt timing, duration, and flow magnitude are highly variable and influence regional climate, geomorphology, and hydrology. Arctic and sub‐arctic regions have sparse long‐term ground observations and these snow‐dominated hydrologic regimes are sensitive to the rapidly warming climate trends that characterize much of the northern latitudes. Passive microwave brightness temperatures are sensitive to changes in the liquid water content of the snow pack and make it possible to detect incipient melt, diurnal melt‐refreeze cycles, and the approximate end of snow cover on the ground over large regions. Special Sensor Microwave Imager (SSM/I) and Advanced Microwave Scanning Radiometer for EOS (AMSR‐E) passive microwave brightness temperatures (T_b) and diurnal amplitude variations (DAV) are used to investigate the spatial variability of snowmelt onset timing (in two stages, ‘DAV onset’ and ‘melt onset’) and duration for a complex sub‐arctic landscape during 2005. The satellites are sensitive to small percentages of liquid water, and therefore represent ‘incipient melt’, a condition somewhat earlier than a traditional definition of a melting snowpack. Incipient melt dates and duration are compared to topography, land cover, and hydrology to investigate the strength and significance of melt timing in heterogeneous landscapes in the Pelly River, a major tributary to the Yukon River. Microwave‐derived melt onset in this region in 2005 occurred from late February to late April. Upland areas melt 1–2 weeks later than lowland areas and have shorter transition periods. Melt timing and duration appear to be influenced by pixel elevation, aspect, and uniformity as well as other factors such as weather and snow mass distribution. The end of the transition season is uniform across sensors and across the basin in spite of a wide variety of pixel characteristics. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

On the energy density of the cosmic microwave background     

A. Dinculescu 《Astrophysics and Space Science》2007,310(3-4):237-239

Starting from the assumption that the radiation source at the origin of the cosmic microwave background (CMB) could not have a luminosity larger than the maximum energy in ordinary matter divided by the minimum time allowed by causality, one arrives at an expression that gives the energy density of CMB as a function of the main cosmological parameters. Also, by defining a radiation charge as the hypothetical charge that opposes the congregation of a cloud of particles around a source of electromagnetic radiation, on arrives at another expression for the energy density of CMB that agrees exactly with the measured value for a value of the Hubble constant equal to 72.09 km s⁻¹ Mpc⁻¹. Both expressions are independent of the redshift.  相似文献   

Very deep X-ray observations of the anomalous X-ray pulsar 4U 0142+614     

N. Rea  E. Nichelli  G. L. Israel  R. Perna  T. Oosterbroek  A. N. Parmar  R. Turolla  S. Campana  L. Stella  S. Zane  L. Angelini 《Monthly notices of the Royal Astronomical Society》2007,381(1):293-300

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The effect of reionization on the cosmic microwave background–density correlation     

Tommaso Giannantonio  Robert Crittenden 《Monthly notices of the Royal Astronomical Society》2007,381(2):819-826

In this paper, we show how the rescattering of cosmic microwave background photons after cosmic reionization can give a significant linear contribution to the temperature–matter cross-correlation measurements. These anisotropies, which arise via a late-time Doppler effect, are on scales much larger than the typical scale of non-linear effects at reionization; they can contribute to degree scale cross-correlations and could affect the interpretation of similar correlations resulting from the integrated Sachs–Wolfe effect. While expected to be small at low redshifts, these correlations can be large given a probe of the density at high redshift, and so could be a useful probe of the cosmic reionization history.  相似文献